A Station Eight Fan Web Site
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First, to answer a previous question (my geek sense is tingling!): Ultimate Kraven was first shown in his mutated form in the first issue of Ultimate Six (an in-canon mini-series which is usually considered as an arc of USM and is even present in USM reprint volumes).
And now, on to the question!
When exactly did Captain Stacy deduce that Peter is Spider-Man? Was it just after Venom revealed that he realized, "Oh, yeah! Duh!" Or did he know before then? (I get the feeling from his ending monologue that he only just figured it out in Identity Crisis.)
Venom was the catalyst.